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Este artículo fue escrito originalmente en Spanish. Se ha traducido automáticamente para su comodidad. Se han hecho esfuerzos razonables para proporcionar una traducción precisa; sin embargo, ninguna traducción automática es perfecta, ni es su intención la de sustituir a un traductor humano. El artículo original en Spanish puede verlo en Materiales en la K 2001

Materials in the K 2001

01/02/2002
The K fair, goes without saying it, is the market where all those who have something to say in the field of plastics display their products. In the field of material things are not different, while they involve a certain difficulty for a specialized means of communication as a universal plastics, given the large range of new products presented, as well as other existing improvements. On these pages we have tried to make a summary of the main, connoisseurs of the impossibility of being exhaustive. In other sections of our magazine, as a thank you plastic or Mercaplast, we have already been reporting on new materials presented on the K and the applications to those that target, and will continue with this work in the upcoming issues. If something is common to most of the suppliers of materials or additives, it is the prominence of the applications, innovation aimed at everyday life in the production plant of its customers. The client, the market actually sends and is he that is in the mind of the companies shown below.

Addiplast

He attended the fair demonstrating its advances in recent years: increased capacity, investments in technologies of production, obtaining certificates of quality, significant increase in turnover. This French producer of compounds (represented in Spain by Brenntag) offers tailor-made compounds, coloured and fireproof, based on PP (Addilene) and PA (Addinyl)

In 1999 the company has invested 4 EC Awards Meuros in new stores and a new line of compounding, carrying capacity to the 18,000 annual T, with 6 double screw extrusion lines. It has already also an extruder of double spindle of laboratory and analysis equipment.

Its compounds are mainly directed to the automotive, electrical, electrical appliances and containers for cosmetics. Some recent innovations include a PP reinforced with five years of stability to UV or compounds of PP of special effects.

Advanced Elastomer Systems

He went to the fair as co-exhibitor with one of its German dealers, Biesterfeld Plastic, and introduced several new features. The new M300 family of thermoplastic Vulcanized Santoprene, for use in automotive applications of soft touch interiors, presents 50% less vaho training compared to other similar products on the market, in values of 1.2 mg, according to the DIN 75201 toebox method B (100 ° C, 16 hours). Colorables grades have advantages similar to black materials, with the advantage of the anti UV protection.

Santoprene TPV 8000 which comply with European standards, has been developed for the Windows market very high profile extruded in what refers to the ability of sealed, aging and behavior in the open.

On the other hand, the POS B100 series is the first linking ABS, PC, blends of ABS/PC, PS, PMMA, ASA and PET, allowing the use of durable anointings without adhesives twin-screw and inyectadores.

Borealis

Among the innovations presented at the fair was Borpact, a polypropylene that combines transparency with high impact resistance, filling the gap between the heterofásicos of high-impact copolymers and the transparent randoms. He also announced the launch of new grades of LLDPE Borstar for films to freezer bags, as well as movies subjected to low temperatures.

DSM Petrochemicals

Created in January 2001 through the merger of DSM Hydrocarbons, DSM Polyethylenes and DSM Polypropylenes, has launched a new generation of copolymers of block of high performance resilient to the impact, under the names Stamylan 83EK10, Stamylan PHC26 P, Stamylan P 66 M 60 and Stamylan P 612MK10. They are the answer to the growing demand to reduce costs and optimize the balance resistance to impact/stiffness/fluency.

Stamylan P 83EK10 provides excellent resistance to impact, even at low temperatures, so it is ideal for applications in which security is of great importance.

Stamylan P PHC26 brings improvements in the impact resistance and surface quality and is suitable for cartons and containers, as well as the container and packaging of pp.

Stamylan P 66 M 60 is a new development with opaque base color, specially developed for all kinds of applications of batteries. Improves the fluidity of previous degrees and its resistance to impact, increasing their chances in the field of the covers for batteries.

Stamylan P 612MK10 reduces considerably the cycles and the thickness of the walls in packaging, thanks to the remarkable improvements in their fluency. Improve the costs in the process of injection without negatively affecting other factors.

This company has also expanded its range of PP homopolymer, among others with the P Stamylan 14E10FB for BOPP film.

Eastman

He has presented the biodegradable copoliéster Eastar Bio, whose first applications are already on the market. It is an aliphatic copoliéster - aromatic semicristalino, translucent, with similar to LDPE tensile strength, high elongation under module, 108 ° c melting point With regard to their transformation properties, highlights its easy processing, superior adhesion, good mechanical properties, compostability, ability to be used as mixing and laminated plates. You could use in conventional equipment for the production of blown film and cast, extrusion of oriented film, coatings and monofilament.

Silk group

At the fair announced an increase in the production of PET of 29%. While the main application are the bottles for various uses, the PET of this company is also aimed at films, thermoforming, and also fields very promising as cosmetics, chemistry, engineering, construction, dairy and beer. The grades SedaPet, SedaPet W, ExtruPet, GlassPet, BasicPet A, BasiPet C are very pure, easy processing by extrusion and injection polyesters.

Kraton

He held his first presence after being acquired by Ripplewood Holdings and exhibited as a 'inventors' of SBC technology. Kraton Polymers include a range of elastomer thermoplastic high performance which, with other ingredients, can improve the appearance and the benefits of mucos products. There are more than 100 different degrees. Among other things, they can be used as an economical solution for the replacement of PVC, that it has launched a range of polymers not-based plasticizers, economic and adjustable to the needs of each application. This is more specifically of the Kraton G range, copolymers block hydrogenated estirénicos which have properties like stability, resistance to oxidation and the weather, high performance at high temperatures, soft touch and can be processed without the use of plasticizers.

Makroform

This joint venture of Bayer and Röhm created in June 2000, wants to become the leader in the field of polycarbonate and polyester plates. Forecasts of growth for massive plates are of 6-8 per cent per annum and the boards of several walls, 10%. Polyester plates could grow even more, between 15 and 20 per cent, although we must bear in mind that part below that the polycarbonate.

From the point of view of the innovations include two new plates: mono Makrolon longlife clear 2099 P and Makrolon mono longlife clear 2099 GX. They are two plaques structured with a blade that is special on both sides to protects against weathering and UV rays. They are intended for exterior applications and are available in widths of 1,650 mm. Typical applications are roofs of all types, greenhouses, winter gardens and bus stops, for example.

Nitroil Performance Chemicals

Spain represented by Synthesar, it showed new developments of the polyurea, an elastomer of the family of polyurethanes is notable because it does not harm the environment. Is it just a spray of two components or elastomer compound casting reactive component and does not contain solvents. Its excellent resistance against chemicals and heat up to 150 ° C, combined with its physical properties, turn this elastomer into a universal product for adhesives, sealants, coatings and protection applications.

The wide range of catalysts for CAT PC and the PC STAB stabilizers for rigid and flexible polyurethane foams was also presented.

PolyOne

PolyOne is the result of the consolidation of the previous M.A. Hanna Company and The Geon Company, produced on September 1 of the year 2000 since its formation, has created six groups of points of production or divisions which manufacture or sell a product or service similar: Engineered Materials and Colors (materials and technical colours), Vinyl Compounds (compounds vinyl), Elastomers and Performance Additives (elastomer and additives) of benefits, Distribution (distribution), Specialty Resins and Formulators (specialized resins and policymakers) and Engineered Films (technical films).

The presence in the Hall K2001 focused on these divisions and to show how PolyOne Corporation "helps people to do wonders with polymers". The capacity of PolyOne combine the products, services and skills of its staff to provide customers with successful applications was exhibited. Among the new products that were featured on the stand the complete range of elastomers is thermoplastic of PolyOne, masterbatches for use in rich final mixes for PET bottles, applications that use compounds PS color sindiotácticos EDGETEK sPS and a new range of additives concentrates. PolyOne has announced the launch of a new type of color (masterbatch) concentrate on Europe. So far, concentrates color (or masterbatches) were scattering the pigment a polymer and turning it into granules 2 to 3 mm in diameter. For high volume applications, such as PET bottles, these granules offer an excellent and effective alternative to the expensive precoloreados compounds. Responsibility is a micropearls system that presents several advantages with respect to the traditional granules and liquid masterbatches. Due to the size of the pearls, offers a very high dispersion in PET blow-molded, which translates into a colored very uniform even for clear dyes. You can also use with lowered ends of less than 0.5%. In addition, it is a much easier to handle than liquid masterbatches product, and the equipment used in its transformation requires a minimum cleaning. On the other hand, one of the latest results of the programmes of development of materials that has launched So.F.TER., partner of the Italian joint venture of Polyone, it has been the introduction of a range of compounds without PVC synthetic leather applications. The latest developments are Forprene 6LH TPE-V (elastomer thermoplastic Vulcanized) and Bergaflex 83 LH (elastomer based on SEBS thermoplastic.)

Polyram

Polyram, Israeli company for the production of compounds of thermoplastics for engineering on the one hand, presented a new degree of compounds of PVDF with good mechanical properties and high resistance to heat and chemicals. He also presented a PE lubricated for coating of inner layers of pipes of HDPE and Bondyra, an agent for glass fibres, mineral and directed to the multilayer extrusion loads.

RadiciPlastics

Revitalize and optimize the use of the polyamide 66 in the sectors of seals and connectors, developing new formulas of Radilon to directly during the polymerization is the most recent challenge of RadiciPlastics to increase productivity. The company is playing with the advantage of being a producer of PA 66 in its chemistry, along with the flexibility of a producer of compounds.

The range of self-extinguishing materials based on phosphorus has been enriched with a new series of materials with improved performance. The names of these materials with Radiflam ARV150AF868 and Radiflam ARV350AF868 and contain between 15 and 35% glass fibre.

Rhodia

He presented Technylstar, with the idea of addressing both transformers of plastic as the manufacturers. This is a nylon of much flow that accelerates the process of production and that offers great versatility from the point of view of the properties and possible applications.

Provides a reduction of at least 10% over the cycle time, requires 20% less of the injection pressure, allows the reduction of 30% in the clamping force and reduced at 40 ° C temperature. These characteristics are that it can be used in electrical and electronic products, as well as a challenging sector such as the automobile which has already shown its interest by Technylstar after trying.

Below is a company specialized in the manufacture of systems for automotive fuels and interior parts. Their products are subject to high demands from the point of view of mechanical strength, as well as the attack of chemicals that should be able to resist. In addition, an excellent surface quality and ability to be painted, is an obligation for his pieces. It is one of the companies that has tested the new Rhodia polyamide, with excellent results. Technylstar SX with 60% of glass fibre is giving the desired result in pieces of the ventilation system. The grid, for example, has been improved and has a surface area of the same quality as the previous one, with 30% of reinforcement. It could also reduce the cycle in more than 20%, the strength of closure by 30% and the temperature of 40 ° C, thus confirming the data of the producer.

Rhodia also used the fair to show the injection technique with water using their PA 6 and PA 66, as well as specific grades for car cooling system water tanks.

It has also developed a series of concepts focused on hybrid solutions of plástico-metal for structural parts.

Röhm

The business area Röhm copolymer of the leading manufacturer of special chemistry, Degussa AG, Düsseldorf, has proposed as a goal achieved a steady growth in the long term from its multinational clients to focus their activities on the demands of the latter. The presentation focused on the areas of application mobility, communication, light and life style. Here we see some examples.

With its divisions Bulk Monomers (monomers standard), Performance Monomers (monomers special) and masses of moulding, the business area of Röhm copolymer is a world leader in the chemistry of methacrylates.

Under the brand name Plexiglas masses of moulding business area offers a full programme of masses of molding standard, special and resistant to the impact for all applications in injection molding and extrusion, e.g. for the automotive and traffic market segment, telecommunications, media of optical data, lighting, construction, household goods, optics and health technique.

In the 2001 K, the business area of Röhm copolymer of Degussa AG presents a new generation of special products for communication techniques included in its range of masses of moulding. High transparency, maximum transmission and a double refraction extremely low are the outstanding features of the masses of moulding Plexiglas in comparison with the polycarbonates usually used in the manufacture of screens for mobile phones.

Currently, the screens of the modern mobile phones from Siemens (SL42, SL45, S45 and S35 models), models 3310 and 3330 of Nokia, as well as the screen of the Nokia terminal for the telematic system for Audi are manufactured with masses of moulding Plexiglas.

These masses of molding also are especially suitable for the lighting of the screens, thanks to its great purity optics, ensuring a uniform illumination of the screen in its entirety.

In the field of compact discs, mass of moulding Plexiglas DQ501 has been specially developed as a material basis for optical storage devices and is characterized primarily by its excellent optical purity and high hardness of the surfacea drop double refraction)< 20="" nanómetros),="" su="" excelente="" transmisión="" que="" alcanza="" el="" 92="" %,="" así="" como="" la="" excelente="" precisión="" en="" la="" representación="" de="" los="" pits="" más="" pequeños="" y="" el="" alto="" módulo="" de="" elasticidad="" que="" permite="" una="" planicidad="" inalterada="" en="" caso="" de="">

One of the criteria of particularly important valuation in the production of DVD that, unlike the DVD5 have two layers of information, is that both halves injection moulded must be absolutely flat, to ensure a uniform and application without inclusions of air of the adhesive for the Union of these two halves.

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SABIC

He announced a new technology for the production of linear alfaolefinas (LAO), together with the German company Linde AG. Both companies have chosen the brand name a-Sablin for the new product resulting from this technology that uses ethylene to a reaction of a stage in the production of C4-C20 + LAO. SABIC to build the first floor of this type with a capacity of 150,000 t / in Saudi Arabia, and could be launched in 2004.

Solvay

Solvay Advances Polymers has launched three new degrees of its line of high performance engineering compounds called Ixef. It is of Ixef 1028/9208, a variant of the standard degree reinforced with 50% glass fibre, of black and printable color laser.

Another novelty is Ixef 1622 (natural and black), which provides a significant improvement in the impact resistance and, thirdly, Ixef 2011, a degree of gloss with wide dispersal of the heat and designed for lamp reflectors and other applications.

Stamax

A module for door of car made from Stamax P, a new thermoplastic composite developed by OC Automotive Solutions and DSM Automotive Polymers was exposed for the first time at the fair, in the same way as other applications as the front-end for the new Mini.

Stamax is a company formed by Owens Corning and DSM to unite efforts in the field of glass fibre reinforced thermoplastics.

In regards to the frontend for the new BMW Mini, with Stamax P have prevented many metal parts, thus reducing the weight and price, and giving the possibility of providing the piece prepared for the Assembly line of the car manufacturer. Stamax P is replacing the GMT and other Engineering Thermoplastics. It's a PP reinforced with fiber glass for the automotive sector. In the case of the piece for mini, the PP is reinforced with 30% long glass fibre. The company collaborates with users in the development of appropriate spindles to process this type of material, in which the fiber's length plays a fundamental role.

Imagen

Victrex

The demand of the Victrex PEEK (distributed in Spain by LVL) reached a record for September 30

in 2001, with sales of 1,600 T, representing an increase of 21% over the same period of the previous year. More than 150 new applications were released last year. This situation produced a mild problem of supply, reason for which the company has decided to expand its capacity up to the annual 2,300 tons, in 2003 will be to 2,800. Also stresses the commitment made by Victrex with the field of medicine, establishing the Invibio Ltd company, to provide solutions with biomaterials for implants.

From the point of view of applications, cannot be the example of the tiny connectors in which this PPEK is being used by the French Radiall SA. It's connectors between two printed circuits, of only 3 mm in height, which can be used in many sectors, such as mobile phones and laptop computers.

Akcros

Akcros introduced numerous products. Lankromark is a family of stabilizers thermal fluid of metallic combinations, among which dominate the bario-cinc and calcio-cinc, as well as stabilizers/activators for PVC foams and already recognized products of bario-cadmio - zinc. The range of calcio-cinc includes "degrees of low toxicity". The stabilizers Lankromark have been developed to offer a wide range of features for conversion and end-use benefits intended to meet the varied requirements of the market. They find application in a wide range of flexible PVC products: from coatings of floor and wall to canvas coverings. Calcio-cinc of low toxicity levels are used in processing materials for applications such as toys or components which have come into contact with food.

Tinstab is a family of organotin stabilizers, mercaptidas and carboxilatos optimized for the transformation of PVC, both flexible and rigid. The formulator may choose within the group grades tailored exactly to the requirements of the application, such as thermal stability, retention of color and transparency, as well as grades approved for use in materials in contact with food. Can be used in injection, extrusion, moulding by blowing and calandrado. Their low addition rates, compared with other stabilizers, make them economically competitive. The Vulcabond products are direct Union agents which improve the adherence of the PVC plastisoles polyester, nylon and other synthetic fibers. Recently joined the Vulcabond KB range a product with a resistance of Union improved to a level of similar addition.

Intercide products offer the plastic protection against the effects of the microbial attack. They are based on several active ingredients, formulated on a range of material carriers and with different physical forms to respond to the wide variety of needs for conversion and end-use benefits. They are widely used in flexible PVC, which often is subject to microbial attack that the plasticizers ingredients in the formula work as food when combined with wet environments in some final applications. Recently, the company has expanded the range to include biocidal products for other plastics. Intercide DP8438F is a solid product in the form granular, intended for use with polyolefins and provide antimicrobial properties to the surface of the plastic.

Ampacet

(Black, white, colours and additives) masterbatches of this company are found in many of the products that we use regularly, such as plastic bottles, packaging for food and non-food products, bag to transport objects and debris. Ampacet also supplies products used in the production of raffia and protection in the indus - films

Trias automotive and metals, as well as open canvas and pipes.

At the fair introduced many new features for low thickness and high-quality films, films for merchandise, agricultural, protective, PP cast and directed, as well as for pipes and the reduction of sediment in the mold.

Cabot

He presented a full range of masterbatches for the production of geomembrane and geotextile. Geosynthetics masterbatches are designed so that the producers of geomembrane added them to base polymers, allowing them to produce the necessary features for different situations. They are compatible with most of the polyethylene, polypropylene and PVC.

Products incorporating varying degrees of black coal of high performance for protection with the deterioration caused by the heat or exposure to UV. Used carbon blacks have been selected for its morphology and ability dispersion, key factors for the resistance to the necessary elements to combine them with the polymer.

Cabot also introduced two new products to its Cabelec range of conductive compounds. Both provide anti-static properties in electronic products. 4701 Cabelec has been developed for extrusion and 4731 Cabelec applications to the field of injection.

Plaswite PS7549 is a new masterbatch that achieves a high opacity and protection against light, designed for packaging of PS for food.

In addition, there were in the K two new black of coal special PC pigmentation and polyester fibers: Black Pearls 4890 and Black Pearls 4560.

Clariant

Pigments and additives of Clariant Division showed their new products and developments in the fields of plastics industry: flame retardants, additives, pigments, waxes, r & d.

Flame retardants: it showed its range Exolit products, developed especially for the electrical and electronics industry Exolit AP 75 X goes to the market of the polyolefins and its properties have been improved in cooperation with suppliers of the industry. Plastics with these retardants have better mechanical resistance and flowing easily. Under the brand name Exolit RP offers a series of products based on red phosphorus, including degrees powder, dispersions and concentrates based on diverse as phenolic, polyamide resin substrates 6 or LDPE.

Additives: Presented the new multifunctional additive Nylostab S-EED, which protects anti UV and is at the same time, an antioxidant as well as a good agent in the manufacture of polyamide fibres. It is also aimed at pipes and cables. Nylostab S-EED is a new compound that also improves the colorabilidad and the intensity of colors of the fibers.

Additives in the Hostanox and Hostavin series are ideal for the stabilization of tubes subjected to high demands.

Pigments: Were two developments: the yellow pigment Polysynthren Yello NG is soluble in amorphous polymers and resistant to heat and light. For its part, PV Fast Yellow H9G VP 2430 is a new easy to disperse pigment and resistant to the alkalis.

In the field of the reds PV Fast network E7B VP 2464 is a pigment that is true for all plastics and stands out for its low dissolved in the melt of polyamide and polyester. And PV Fast THI network 4 G VP 2499 is a new red yellow pigment that also stands out for its heat resistance, weather and light.

It can also noted that, under the name DrizPearls, is being developed in Clariant a new physical form. The pigments are the fine granules made with spherical particles of an average of 200 Micron size.

Great Lakes Chemical

Great Lakes Chemical Corporation introduced 12 new products in the K. 2001.

Mixtures of stabilizers for polymers. Their solutions combine stabilizers for polymers of the wide range of Great Lakes with additives provided by other sources. These mixtures, which are called Anox NDB (No Dust Blends, or mixtures without dust), combining specific components in a dust-free shape. The following products, mixtures made using the technology of the company, were presented at the fair

Mixtures based on Alkanox to improve the hydrolytic stability in a number of applications-there were two based in Alkanox P-24 optimized blends that offer more hydrolytic stability compared to the molecule of Alkanox P24 used as pure additive. The benefits due to the combination of the physical form of Anox NDB with a carefully selected synergistic composition.

Stabilizer Anox 330 for the production of polyolefins and other plastic applications.-is a stabilizer that protects against long term thermal aging and provides excellent benefits when used in the production of polyolefins and other plastic applications.

Mixed binary Anox antioxidants they contain antioxidant phenolic disabled and phosphites-Anox BB2777 and Anox BB2888 are synergistic binary mixtures that are used to protect polymers during processing and long term thermal aging. Both mixtures contain Lowinox 1790, high performance produced by Great Lakes, antioxidant and Alkanox 240, stabilizer used in prosecutions. Thanks to the reduced volatility of these components, new mixtures can be used at comparatively high temperatures and at the same time provide excellent resistance to removal of polymeric compounds.

Optimized desactivadoras mixtures of phenol / metal Anox MDAO11 and Anox MDAO85.-both mixtures are composed of Lowinox MD 24 and Anox 20, antioxidant phenolic prevented. Anox MDAO11 has a ratio of 1: 1 and Anox MDAO85 2: 1 of these components. Each blend is sold in the form of powder or granules. Thanks to its combination of qualities polymer provides excellent protection against Autoxidation processes that can occur in the presence of transition metal ions as for example metal components of cables or waste of catalysts.

Mixing liquid picture and termoestabilizadoras high performance Lowilite for Polyurethanes-Lowilite UV B1260 and Lowilite UV B1211 offer effective protection against degradation of color due to prolonged exposure to light and heat in application of polyurethane.

The flame retardants

Great Lakes offers a wide range of bromine, phosphorus and antimony flame retardant products. The products presented in K 2001 include: Reofos NPH, retardant halogen for car seats-free; retardant Firemaster 550 for polyether and polyester foams; brominated retardant Firemaster 2100 of oxide no of diphenyl of general application to a number of polymers.

Delta Tecnic

Deltavinil is a wide range of masterbatches for the technical needs of the color in practically all the industrial sectors of PVC plastic and rigid. Deltavinil C is a masterbatch PVC-based industries of the cable, profiles, injection, pipe, film and calendering. A Deltavinil is intended for all those applications with special requirements for the industry of food packaging, toys, medical sector, etc. And Deltavinil MP, with base PVC, is supplied in the form of micro-pellet. It improves the dilution and replaced the pigment dispersions in powder or paste in the industry of the calendering, pipes, profiles, etc. The size of the this masterbatch pellets also allows the different color mixing unit, getting a perfect homogeneity dl color. He also presented the range of masterbatches Deltaplast, pellets, powder and paste for PVC and other polymers. With variants S, P, BT and EV cover the different needs of different sectors.

Stephan Schmidt

It has developed functional loads for a wide range of applications, such as chemicals for the construction, adhesives, rubbers, plastics or paints, marketed under the name Capsil.

Capsil 2002 CSM 1Tis and Capsil 2004 CSM 2MA, for example, are loads multicomponent developed specially for acrylic systems. They allow a higher load content without damaging the system.

Tramaco

This German company presented its blowing agents, agents nucleators, stabilizers cellular, agents antistatic etc., a complete range of additives for foam technology.

Tracel blowing agents have been extended with new grades of low temperature and allowing the company to cover a range of temperatures of work from 120 to 350 ° C.

They are available in SCB or masterbatches, with content in soplante agent of 5-90%.

Related Companies or Entities

Clear group - Corporación Levantina de Artículos, S.L.
Lati Industria Termoplastici SpA - Sucursal en España
Röhm Ibérica, S.A.
Siemens, S.A. - Smart Infrastructure

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